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Mitigation of NOX Emissions and Enhancement of Combustion Characteristics Using Nano-Emulsified Jatropha B20 Biodiesel in a Diesel Engine

Abstract

This study experimentally investigates the influence of Al?O? nanoparticle addition on the combustion, performance, and emissions of emulsified Jatropha biodiesel in a compression-ignition engine. An emulsified fuel blend comprising 88% Jatropha methyl ester (JME), 10% water (v/v), and 2% surfactant (B20W10) was prepared using ultrasonication, into which Al?O? nanoparticles were dispersed at concentrations of 25 ppm and 50 ppm. Tests were conducted at varying loads under constant speed to evaluate performance, combustion, and emission characteristics. Among the tested fuels, B20W10Al50 yielded the best outcomes, achieving a 2.03% increase in brake thermal efficiency (BTE) and a 3.84% reduction in brake specific fuel consumption (BSFC) compared to diesel, with statistical analysis confirming the significance of these improvements. Combustion analysis showed a modest increase in peak in-cylinder pressure for B20W10Al50. Emission reductions were substantial relative to diesel: unburned hydrocarbons decreased by 40%, CO by 66.7%, NOx by 22.7%, and smoke opacity by 41.7%. These findings demonstrate that nanoparticle-assisted emulsification can address the common biodiesel trade-offs between efficiency and NOx formation. The study highlights B20W10Al50 as a promising formulation for sustainable transport applications, while also noting the need for further research on long-term nanoparticle stability, injector compatibility, and durability under real-world operating conditions.

Keywords

Biodiesel , Emulsion, Surfactant, Performance, Emission

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References

  1. El-Shafay AS, Mujtaba MA, Riaz F, Gad MS. Investigating the role of hybrid binary Feedstocks (waste cooking oil, palm oil, and jatropha oil blends) in biodiesel production: engine performance, emissions, and combustion characteristics. Case Studies in Thermal Engineering. 2025 Jul 16:106688.
  2. Roy A, Dabhi Y, Brahmbhatt H, Chourasia SK. Effect of emulsified fuel based on dual blend of Castor-Jatropha biodiesel on CI engine performance and emissions. Alexandria Engineering Journal. 2021 Feb 1;60(1):1981-90.
  3. Raman LA, Deepanraj B, Rajakumar S, Sivasubramanian V. Experimental investigation on performance, combustion and emission analysis of a direct injection diesel engine fuelled with rapeseed oil biodiesel. Fuel. 2019 Jun 15;246:69-74.
  4. Raheman H, Kumari S. Combustion characteristics and emissions of a compression ignition engine using emulsified jatropha biodiesel blend. Biosystems engineering. 2014 Jul 1; 123:29-39.
  5. Kumar N, Raheman H. Characterization of nano-oxide added water emulsified biodiesel blend prepared with optimal emulsifying parameters. Renewable Energy. 2020 Jan 1;145:308-17.
  6. Zahan KA, Kano M. Technological progress in biodiesel production: an overview on different types of reactors. Energy Procedia. 2019 Jan 1;156:452-7.
  7. Vellaiyan S. Improved jatropha biodiesel yield and engine performance using carbon nanotube-copper oxide nanocatalyst and ammonium hydroxide emulsion for scalable clean energy solutions. Biomass and Bioenergy. 2025 Oct 1;201:108120.
  8. Zhou L, Li F, Sui M, Wang W, Wang H. Effects of copper stearate on the premixed combustion and emission performance of jatropha biodiesel. Renewable Energy. 2025 Jun 15;246:122925.
  9. Gopidesi, R.K. and Premkartikkumar, S.R., 2023. Evaluating the hythane/water diesel emulsion dual fuel diesel engine characteristics at various pilot diesel injection timings. Materials Today: Proceedings, 80, pp.3033-3037.
  10. Rambabu R, Sridevi G, Kruthiventi SS, Masthanvali PS, Borigorla V, Kalyanamanohar V. Effects of Compression Ratio on a Diesel Engine Powered by Tamarind Seed Biodiesel Blend. International Journal of Vehicle Structures & Systems. 2023;15(6):793-6.
  11. Vellaiyan, S., Subbiah, A. and Chockalingam, P., 2020. Effect of titanium dioxide nanoparticle as an additive on the exhaust characteristics of diesel-water emulsion fuel blends. Petroleum Science and Technology, 38(3), pp.194-202.
  12. Namasivayam, A.M., Korakianitis, T., Crookes, R.J., Bob-Manuel, K.D.H. and Olsen, J., 2010. Biodiesel, emulsified biodiesel and dimethyl ether as pilot fuels for natural gas fuelled engines. Applied Energy, 87(3), pp.769-778.
  13. Gopidesi RK, Sr P, Dhana Raju V. Mitigation of harmful exhaust pollutants of DI diesel engine using emulsified fuel and hythane gas in a dual-fuel mode. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. 2025 Dec 31;47(1):3987-4009.
  14. Melo-Espinosa EA, Piloto-Rodríguez R, Goyos-Pérez L, Sierens R, Verhelst S. Emulsification of animal fats and vegetable oils for their use as a diesel engine fuel: An overview. Renewable and Sustainable Energy Reviews. 2015 Jul 1;47:623-33.
  15. Gopidesi RK, Selvi Rajaram P. A review on emulsified fuels and their application in diesel engine. International Journal of Ambient Energy. 2022 Dec 31;43(1):732-40.
  16. Yang, W.M., An, H., Chou, S.K., Chua, K.J., Mohan, B., Sivasankaralingam, V., Raman, V., Maghbouli, A. and Li, J., 2013. Impact of emulsion fuel with nano-organic additives on the performance of diesel engine. Applied energy, 112, pp.1206-1212.
  17. Prasad, G.V.L. and Gupta, A.V.S.S.K.S., 2016. Role of nano additive blended Karanja biodiesel emulsion fuel on performance and emission characteristics of diesel engine (No. 2016-28-0165). SAE Technical Paper.
  18. Gopidesi RK, Sankar GR, Kumar AP, Kumar AS, Srimal B. Evaluating the performance and emission characteristics of ci engine with waste plastic oil. Int. J. Mech. Prod. Eng. Res. Dev. 2019;9(3):2019109.
  19. Abuelnuor AA, Wahid MA, Mohammed HA, Saat A. Flameless combustion role in the mitigation of NOX emission: a review. International journal of energy research. 2014 Jun 10;38(7):827-46.
  20. Rai, R.K. and Sahoo, R.R., 2021. Impact of different shape based hybrid nano additives in emulsion fuel for exergetic, energetic, and sustainability analysis of diesel engine. Energy, 214, p.119086.
  21. Varatharajan K, Cheralathan M, Velraj R. Mitigation of NOx emissions from a jatropha biodiesel fuelled DI diesel engine using antioxidant additives. Fuel. 2011 Aug 1;90(8):2721-5.
  22. Chakrabarti MH, Ali M, Usmani JN, Baroutian S, Saleem M. Technical evaluation of pongame and Jatropha B20 fuels in Pakistan. Arabian Journal for Science and Engineering. 2013 Apr;38(4):759-66.
  23. Hashimoto N, Nishida H, Ozawa Y. Fundamental combustion characteristics of Jatropha oil as alternative fuel for gas turbines. Fuel. 2014 Jun 15;126:194-201.
  24. Sahoo PK, Das LM. Combustion analysis of Jatropha, Karanja and Polanga based biodiesel as fuel in a diesel engine. Fuel. 2009 Jun 1;88(6):994-9.
  25. Vellaiyan, S., Subbiah, A. and Chockalingam, P., 2018. Combustion, performance, and emission analysis of diesel engine fueled with water-biodiesel emulsion fuel and nanoadditive. Environmental Science and Pollution Research, 25(33), pp.33478-33489.
  26. Yan L, Xu Z, Wang X. Influence of nano-silica on the flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings. Progress in Organic Coatings. 2017 Nov 1;112:319-29.
  27. Karthikeyan S, Prathima A. Emission analysis of the effect of doped nano-additives on biofuel in a diesel engine. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. 2016 Dec 16;38(24):3702-8.
  28. Sadhik Basha, J. and Anand, R.B., 2011. Role of nanoadditive blended biodiesel emulsion fuel on the working characteristics of a diesel engine. Journal of Renewable and Sustainable energy, 3(2).
  29. Bala Prasad, K., Dhana Raju, V., Ahamad Shaik, A., Gopidesi, R.K., Sreekara Reddy, M.B.S., Soudagar, M.E.M. and Mujtaba, M.A., 2025. Impact of injection timings and exhaust gas recirculation rates on the characteristics of diesel engine operated with neat tamarind biodiesel. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 47(1), pp.7767-7785.
  30. Basha SA, Gopal KR. A review of the effects of catalyst and additive on biodiesel production, performance, combustion and emission characteristics. Renewable and Sustainable Energy Reviews. 2012 Jan 1;16(1):711-7.
  31. Deepanraj B, Senthilkumar N, Mala D, Sathiamourthy A. Cashew nutshell liquid as alternate fuel for CI engine—optimization approach for performance improvement. Biomass conversion and biorefinery. 2022 May;12(5):1715-28.
  32. Van Der Graaf S, Schroën CG, Boom RM. Preparation of double emulsions by membrane emulsification—a review. Journal of Membrane Science. 2005 Apr 1;251(1-2):7-15.
  33. Chen G, Tao D. An experimental study of stability of oil–water emulsion. Fuel processing technology. 2005 Feb 25;86(5):499-508.

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